In a sneak peek at the couple's wedding, which took place at a private residence in Montecito, California on Saturday night, the 30-year-old reality star is blushing as she stands hand-in-hand with her now husband, just moments before their nuptials.
E! Entertainment gave fans a sneak preview of the big day last night, ahead of the full ceremony, which will air on the network in early October.
The big moment: Beaming and beautiful bride Kim Kardashian is the picture of happiness as she is about to exchange vows with fiance Kris Humphries
It's time! In a sneak peek at the couple's wedding video, the 30-year-old reality star is blushing as she stands hand-in-hand with her now husband, just moments before their nuptials
She has her veil off her face with a jeweled headpiece containing diamonds, 'dripping' on to her forehead.
Her make-up whilst striking, was a more paired down look for the reality star, and she wore her hair in a simple up-do.
Excited: Kim flashes her famous grin to her guests as she walks down the seemingly endless white and black carpeted aisle to classical music, all whilst on the arm of her step father, Bruce Jenner
As she finally makes it down to Kris, who is equally dapper dressed in a cream peak lapel tuxedo jacket, black tuxedo pants with white shirt and white bow tie by Ermenegildo Zegna, the couple can't stop smiling at one another.
They then proceed to look around with amazement at their 450-strong guestlist before the ceremony gets underway.
Beautiful: Co-maids of honour Kourtney, 32, and Khloe, 27, are also seen in their the cream strapless gowns with their brunette tresses down in loose waves
And it appears that Kim looked to the biggest wedding of the year - William and Kate's - for inspiration for her bridal party.Co-maids of honour Kourtney, 32, and Khloe, 27, are also seen in the clip in their cream strapless gowns with their brunette tresses down in loose waves.
Kim's mother Kris Jenner also takes a moment before the ceremony to pose with her two daughters and Kim's half sisters and bridesmaids, Kylie, 15, and Kendall, 14.
Family snaps: Kim's mother Kris Jenner also takes a moment before the ceremony to pose with her two daughters and Kim's half sisters and bridesmaids, Kylie, 15, and Kendall, 14
Kris, 55, also wears a Vera Wang-designed dress; a strapless white gown with an over-the-top bow across the bodice, while the two teenagers wear matching strapless dresses with fishtail hems.And while Kim and the wedding party can only be described as flawless, it appears that it was little Mason who nearly steals the show, with the toddler walking down the aisle in a miniature cream tuxedo.
At first he was held by his mother Kourtney who herself had a near-fall as she walked down the aisle holding her son, who played ring bearer in the ceremony.
And while she steadied herself, though, little Mason, 21 months, zoomed down the aisle ahead of her.
Lucky man: Kris look like the cat that got the cream as he waits for his bride
Among the guests at the wedding, Eva Longoria, who was there with her partner Eduardo Cruz, was spotted seated in the crowd, adhering to the black and white theme in monochrome black.Guest and E! News reporter Ken Baker, who was among guests at the lavish affair, said that Kim received a round of applause as soon as she stepped onto the grandiose aisle, but the reality star made sure to keep her cool.
'When Kim walked into the courtyard and people saw her, they started playing the music - she was with Bruce and they saw her in the dress, people started to applaud... it was so dramatic, she looked flawless,' he said.
'Kim was very low-key, she seemed really mellow and she sort of set the tone for the whole night... It was a very mellow night, Kris is a very mellow guy and it felt very intimate.'
He revealed that the whole 30-minute ceremony, which started at approximately 6.30pm, was flawless and had personal touches.
'It was well planned, well executed and everything went really smoothly,' he said.
Star-studded: Among the guests at the wedding, Eva Longoria is spotted in the crowd, adhering to the black and white theme in monochrome black
The pastor also reportedly warned the couple that marriage isn't always a bed of roses.
'He was also speaking very candidly to the couple, saying "Look you can go from being really happy and blissful to having a mediocre marriage, if you don't work on it."' Baker revealed.
The ceremony was watched not only by the couple's families, but also celebrity guests including Ryan Seacrest, Lindsay Lohan, Eva Longoria, Mel B, Venus and Serena Williams, Avril Lavigne and Demi Lovato.
A long way down: The black and white carpeted aisle was endless on the grounds of the Montecito estate
Following the ceremony, the action moved to a separate tent with the bride changing into a second Vera Wang mermaid gown with more Chantilly lace on the bodice and hand-cut organza petals on the skirt, with the reality star expected to change into a third creation.
Soul singer Robin Thicke introduced 'Mr and Mrs Humphries' and sang his song Angels for the couple's first dance as husband and wife, then Let's Stay Together.
Following the ceremony, bridal designer Vera Wang Tweeted: 'Wow! @KimKardashian What a joyous, beautiful, magical night! Wishing you and Kris all the blessings in the world xx Vera.
Soul singer Robin Thicke introduced 'Mr and Mrs Humphries' and sang his song Angels for the couple's first dance as husband and wife, then Let's Stay Together.
Following the ceremony, bridal designer Vera Wang Tweeted: 'Wow! @KimKardashian What a joyous, beautiful, magical night! Wishing you and Kris all the blessings in the world xx Vera.
Adorable: Little Mason nearly stole the show, with the adorable 21-month-old toddler making his way down the aisle in a miniature cream tuxedo
The order of service also included an emotional tribute to Kris Humphries' late grandparents and Kim's late father Robert Kardashian.
Kim wrote: 'I so wish my dad could be here today to walk me down the aisle. But I know in a way he is here, and I feel his loving presence all around me. I love and miss you, dad.'
The wedding breakfast was made by celebrity chef Wolfgang Puck with a starter of buffalo mozzarella and tomato salad, and a choice of hand-formed agnolotti with sweet corn mascarpone and summer truffles, or roast chicken with Yukon Gold potato puree, caramelized brussels sprouts and summer truffles for the main course.
Guests at the wedding were treated to high security measures including metal detectors and having their phones and cameras taken away.
Several celebrities were spotted arriving at the venue, with Mel B and her husband Stephen Belafonte sticking to the black and white dress code, with the former Spice Girl looking pretty in a white strappy dress.
Lavish: The wedding could only be described as grand
Talk show host George Lopez arrived in a black suit, shirt and tie, with actor-turned showbiz presenter Mario Lopez also looking smart.
The groom also found time to tweet his excitement mere moments before arriving at the alter.
Celebrity guests: Kim's step-brother Brody Jenner and his girlfriend Avril Lavigne were matching in head-to-toe black
The bride and groom have enjoyed spectacular weather for their big day, with the sun setting over a cloudless sky as they said their 'I Do's'.
Guests began arriving at the wedding venue 90 minutes before the ceremony in blacked-out shuttle buses.
The wedding comes as a big pay day for Kim. U.S. magazine People has bought the rights for the exclusive photographs for a cool $1.5million.
Here comes the boss! Kardashian producer Ryan Seacrest and his actress girlfriend Julianne Hough waved as they arrived
Designated driver: R&B singer Ciara drove herself to the ceremony
Peekaboo: Kim's former Dancing with the Stars partner Mark Ballas, who is rumoured to have choreographed the couple's first dance - arrived with Cheryl Burke
Plus, she has already pocketed $300,000 for the engagement announcement back in May and another $100,000 from OK! magazine for the bridal shower photos.
Just hours before saying her 'I dos', Kim tweeted her fans, telling them: 'Anxious,excited,emotional 3words 2describe what Im feeling right now @KimKardashian I LOVE U tomorrow will b MAGICAL.'
She also posted a message on her official website: 'Today is the day! I can’t believe it’s finally here! Thank you so much to everyone who made this day happen!!!!!'
Kim's wedding will be aired in full on the E! network two-part special on October 9th and 10th.
Mr and Mrs: Kim and Kris emerge from their Montecito hotel this morning a married couple